| 세션명 | Graduate Student Oral Session (I) (English) |
|---|---|
| 발표장 | 제9회장 |
| 논문코드 | 1O9-12 |
| 발표일 | 2021-10-21 |
| 발표시간 | 16:55-17:10 |
| 논문제목 | Semi-flexible colloidal chains consisting of patchy micelles of block copolymers as a nanoscale analogue of conventional polymers |
| 발표자 | 이경현 |
| 발표자 소속 | 서울대학교 |
| 저자 | 이경현, 손병혁† |
| 소속 | 서울대학교 |
| 논문초록 | Colloidal particles can be utilized as an effective building block for a variety of superstructures such as colloidal molecules and lattices through self-assembling processes. In particular, they can assemble into a linear colloidal chain by directional attraction with orthogonal repulsion between the particles. A colloidal chain can be considered as a nanoscale polymer consisting of colloidal monomers. In this study, we first polymerized patchy micelles of block copolymers into a linear colloidal chain and then coated them onto a solid substrate. We evaluated their persistence and contour lengths, which allowed the assessment on the flexibility of colloidal chains. According to the analysis, we can describe the colloidal chains semi-flexible and explain their conformations by the worm-like chain model for conventional polymers. In addition, we were able to produce a self-supporting film of the colloidal chains, which has microscopic pores due to the semi-flexible nature of the chains. |
THE POLYMER SOCIETY OF KOREA